|
|
(S)-2-Hydroxy-2-(4-hydroxyphenyl)acetate + O2 + H+ <=> 4-hydroxybenzaldehyde + CO2 + H2O2
|
1.1.3.19
4-hydroxymandelate oxidase (decarboxylating)
|
–
|
K
|
|
BRENDA:
BR36736
KEGG:
R02673
MetaCyc:
4-HYDROXYMANDELATE-OXIDASE-RXN
|
|
|
|
(S)-2-Hydroxy-2-(4-hydroxyphenyl)acetate + O2 <=> 4-hydroxyphenylglyoxylate + H2O2
|
1.1.3.46
4-hydroxymandelate oxidase
|
–
|
K
|
|
BRENDA:
BR50849
KEGG:
R06633
MetaCyc:
RXN-15300
|
|
|
|
(S)-2-Hydroxy-2-(4-hydroxyphenyl)acetate <=> 4-Hydroxy-D-mandelate
|
5.1.2.2
mandelate racemase
|
–
|
BMK
|
|
BRENDA:
BS186625
KEGG:
R04161
MetaCyc:
HYDROXY-MANDELATE-RACEMASE-RXN
|
|
|
|
4-hydroxyphenylpyruvate + O2 <=> (S)-2-Hydroxy-2-(4-hydroxyphenyl)acetate + CO2
|
1.13.11.46
4-hydroxymandelate synthase
|
–
|
K
|
|
BRENDA:
BR29129
KEGG:
R06632
|
|
|
|
(S)-Mandelate + tetrahydropteridine + O2 <=> (S)-2-Hydroxy-2-(4-hydroxyphenyl)acetate + a_4a-hydroxy-5,6,7,8-tetrahydropteridine
|
1.14.16.6
mandelate 4-monooxygenase
|
–
|
K
|
|
BRENDA:
BR47608
KEGG:
R03794
|
|
|
|
(S)-2-Hydroxy-2-(4-hydroxyphenyl)acetate + acceptor <=> 4-hydroxyphenylglyoxylate + reduced_acceptor
|
1.1.99.31
(S)-mandelate dehydrogenase
1.1.99.B9
|
–
–
|
K
|
|
BRENDA:
BS438524
KEGG:
R04160
|
|
|
|
(S)-2-Hydroxy-2-(4-hydroxyphenyl)acetate + electron-transfer_quinone <=> 4-hydroxyphenylglyoxylate + electron-transfer_quinol
|
1.1.5
|
–
|
M
|
|
MetaCyc:
4-HYDROXYMANDELATE-OXY-RXN
|
|
|
|
(S)-Mandelate + tetrahydropteridine + O2 <=> (S)-2-Hydroxy-2-(4-hydroxyphenyl)acetate + 4a-hydroxytetrahydropteridine
|
1.14.16.6
mandelate 4-monooxygenase
|
–
|
|
|
MetaCyc:
MANDELATE-4-MONOOXYGENASE-RXN
|
|
|
|
(S)-Mandelate + tetrahydropteridine <=> (S)-2-Hydroxy-2-(4-hydroxyphenyl)acetate + dihydropteridine + H2O
|
1.14.16.6
mandelate 4-monooxygenase
|
–
|
|
|
BRENDA:
BS355946
|
|